组合材料方法研究膜厚对Ni/SiC电极接触性质的影响

采用组合材料方法研究了金属Ni膜厚对Ni/SiC接触性质的影响.16个膜厚均为18 nm的Ni/SiC电极具有较为一致的肖特基接触性质;膜厚从10 nm增加到160 nm,肖特基接触的电流-电压（I-V）曲线随膜厚发生显著变化.分析表明这种变化源于膜厚对理想因子n和有效势垒高度Ф_B的影响.1000℃快速退火后,这些肖特基接触都转变为欧姆接触,Ni₂Si是主要的生成物.I-V曲线测 关键词： 碳化硅 肖特基接触 欧姆接触 组合材料方法     

有机薄膜晶体管中接触效应的研究

研究了接触效应对有机薄膜晶体管性能的影响.首先在n型重掺杂Si片上制备了以M_OO₃修饰的Al电极为源漏电极的Pentacene基OTFTs(organic thin film transistors),器件场效应迁移率μ_ef达到0.42 cm²/V ·s,阈值电压V_T为-9.16 V,开关比4.7×10³.通过中间探针法,对器件电势分布做了定性判断 关键词： 有机薄膜晶体管 场效应迁移率 接触效应 电荷漂移     

表面化学处理和退火对p-GaN/ZnO:Ga接触特性的影响

ZnO∶Ga(GZO)透明电极沉积在p-GaN表面,用作透明电流扩展层。直接沉积在p-GaN上的p-GaN/GZO存在较大的势垒,容易形成肖特基接触,而良好的欧姆接触对功率LED器件至关重要。为了降低接触势垒,采用盐酸和氢氧化钠溶液对GaN表面进行去氧化层处理,并对p-GaN/GZO进行退火处理,研究表面处理和退火对p-GaN/GZO接触特性的影响。研究表明:碱性溶液处理有利于降低接触势垒;退火处理后,接触势垒略有增加。     

微结构接触界面热阻

微纳米结构的接触热传输是热电转换、超导冷却、集成芯片散热等高技术领域面临并必须着力解决的技术问题,它区别于宏观热传输,具有为尺度依赖效应和多个微观特征量。文中从微结构接触热传输阻力角度出发,探讨了接触热阻及界面热阻区别,阐释了微尺度的特征量,接触界面热阻实验及理论研究方法、实验参数的测量,接触热阻及界面热阻的材料选择。通过接触界面热阻这些方面的研究,为研究接触界面热阻研究提供了较全面的参考。     

用电位差计校正电表实验的仪器故障判断与排除

用电位差计校正电表实验是主要针对工科学生所开的一个电学实验。由于仪器较多容易出的故障也较多,所以怎样根据仪器故障现象尽快对故障可能存在的部位作出判断,然后排除故障,是实验课能否顺利进行的根本保证。     

聚乙二醇的纳米二氧化硅分散系动态湿润特性

流体动态湿润在工业生产和高新技术的开发中有广泛应用,非牛顿流体动态湿润研究正处于起步阶段,并有着相对于牛顿流体更为实际的应用前景和价值。本文研究了一类具有复杂流变性的聚乙二醇的二氧化硅纳米颗粒分散体系的动态湿润特性。通过液滴铺展法得到了液滴半径随铺展时间的变化关系,以及动态接触角随接触线移动速度的变化关系的实验数据。实验结果表明,该类流体在云母表面上完全铺展,R～t关系符合Tanner定律,结合Starov的理论,分析R～t数据认为该类流体的中剪切速率阶段,即包含剪切增稠段的流变性对动态湿润有重要的影响。现有的动态接触角理论没有针对该类复杂流变流体的专用模型,研究发现分子运动理论模型不考虑黏性耗散,不仅适用于牛顿流体,对本文的θ_D～U数据同样能很好地描述,拟合参数符合物理意义。     

Electrical characteristics of Pt-ZnO Schottky nano-contact

The electrical characteristics of Pt-ZnO Schottky nano-contact have been studied. Well aligned ZnO nanorod arrays were synthesized by two-step wet-chemical method. A Pt-coated conducting probe of atomic force microscope was placed on the head face of the ZnO nanorod, thereby forming a Pt-ZnO nano-contact. The I-V characteristic curve shows that the Pt-ZnO nano-contact exhibits rectifying effect, like a Schottky diode with an ideality factor of 3.2 and a reverse-bias breakdown voltage more than -10 V. The st...     

Improvement in the blood compatibility of polyvinylidene fluoride membranes via in situ cross‐linking polymerization

In this study, we have provided a highly efficient, convenient, and universal protocol for preparing polyvinylidene fluoride (PVDF) membranes with low blood contact activation via in situ cross‐linking copolymerization of 2‐hydroxyethl methacrylate (HEMA) and acrylic acid (AA) in a solution of PVDF. The modified membranes were prepared from PVDF solution by phase inversion technology. The composition and morphology of the modified membranes were confirmed by attenuated total reflectance‐Fourier transform infrared (ATR‐FTIR) spectroscopy, thermogravimetric (TG) analysis, and scanning electron microscopy (SEM). Protein adsorption, clotting time, and contact activation on the modified PVDF membranes were systematically studied, the results indicating that after the incorporation of AA and HEMA, the modified PVDF membranes possessed anticoagulant properties in addition to low contact activation of blood components when in contact with blood. Therefore, fluorinated PVDF membranes with surfaces enriched with carboxyl and hydroxyl groups possessed the potential for use in long‐term blood‐contacting devices.     

A method to prepare gels with controllable morphology through a three‐phase system

Traditional methods for preparing hydrogels with specific morphology need molds with different shapes, which should bring about a complicated process. In order to control the size and morphology of hydrogels conveniently, a new simple synthesis method was advanced to prepare the gels. In this method, the prepolymer solution achieves diffusion in the interface between the upper oil phase and lower hydrogel matrix, which constitutes a three‐phase system, and the morphology of prepared gels was determined by the balanced diffusion status of the prepolymer solution. Hence, through controlling the composition and character of the three different phases in this system, the balanced diffusion status could be adjusted because of the changed interaction acting on the prepolymer solution diffused in the phase interface. The common rule with regards to the resulting morphology of prepared gels was investigated by surface tension analysis. The results prove that this synthetic method is feasible in preparing many kinds of hydrogels with controllable morphology as a common approach.     

二硫化钨/石墨烯异质结的界面相互作用及其肖特基调控的理论研究

采用第一性原理方法研究了二硫化钨/石墨烯异质结的界面结合作用以及电子性质,结果表明在二硫化钨/石墨烯异质结中,其界面相互作用是微弱的范德瓦耳斯力.能带计算结果显示异质结中二硫化钨和石墨烯各自的电子性质得到了保留,同时,由于石墨烯的结合作用,二硫化钨呈现出n型半导体.通过改变界面的层间距可以调控二硫化钼/石墨烯异质结的肖特基势垒类型,层间距增大,肖特基将从p型转变为n型接触.三维电荷密度差分图表明,负电荷聚集在二硫化钨附近,正电荷聚集在石墨烯附近,从而在界面处形成内建电场.肖特基势垒变化与界面电荷流动密切相关,平面平均电荷密度差分图显示,随着层间距逐渐增大,界面电荷转移越来越弱,且空间电荷聚集区位置向石墨烯层方向靠近,导致费米能级向上平移,证实了肖特基势垒随着层间距的增加由p型接触向n型转变.本文的研究结果将为二维范德瓦耳斯场效应管的设计与制作提供指导.